发明名称 |
PROCESS FOR THE PRODUCTION OF SILANE PRODUCTS FROM CALCIUM SILICIDE |
摘要 |
<p>A process for preparing a reaction product including a silane product includes step (i), (ii), and (iii). Step (i) is contacting an organohalide with a calcium silicide at a temperature from 300 °C to 700 °C to form the reaction product including a spent reactant and the silane product. The silane product has formula RmHnSiX(4-m-n), where each R is independently a monovalent organic group, each X is independently a halogen atom; subscript m is 0 to 4; subscript n is 0 to 2; and a quantity (m + n) is 0 to 4. Step (ii) is contacting, at a temperature from 200 °C to 1400 °C, the spent reactant with a silane of formula HaRbSiX(4-a-b), where subscript a is 0 to 4, subscript b is 0 or 1, a quantity (a + b)≤4. The silane of formula HaRbSiX(4-a-b) is distinct from the silane product of formula RmHnSiX(4-m-n). When the quantity (a + b) < 4, then step (ii) further includes contacting the spent reactant with H2; thereby forming a reactant. Step (iii) is contacting the reactant formed in step (ii) with an additional organohalide at a temperature from 300 °C to 700 °C to form an additional silane product of formula RmHnSiX(4-m-n). Steps (ii) and (iii) are performed separately and consecutively after step (i).</p> |
申请公布号 |
WO2014172034(A1) |
申请公布日期 |
2014.10.23 |
申请号 |
WO2014US25583 |
申请日期 |
2014.03.13 |
申请人 |
DOW CORNING CORPORATION |
发明人 |
ANDERSON, KURT, E.;DASH, ASWINI, K.;HALL, CHARLES, ALAN;KATSOULIS, DIMITRIS;WINELAND, JONATHAN, DAVID |
分类号 |
C07F7/08;C01B33/06;C01B33/107;C07F7/12 |
主分类号 |
C07F7/08 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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