| 主权项 |
1. A metal-triazolate (MET) framework comprising a plurality of cores of structural Formula I:wherein,
M1, M2 and M3 are independently selected metal, metals ions or are absent, and wherein at least two of M1, M2 and M3 are metal or metal ions; R1-R2 are independently selected from the group consisting of H, optionally substituted FG, optionally substituted (C1-C6)alkyl, optionally substituted (C1-C6)alkenyl, optionally substituted (C2-C6)alkynyl, optionally substituted hetero-(C1-C6)alkyl, optionally substituted hetero-(C1-C6)alkenyl, optionally substituted hetero-(C2-C6)alkynyl, optionally substituted cycloalkyl, optionally substituted cycloalkenyl, optionally substituted aryl, optionally substituted heterocycle, optionally substituted mixed ring system, —C(R7)3, —CH(R7)2, —CH2R7, —C(R8)3, —CH(R8)2, —CH2R8, —OC(R7)3, —OCH(R7)2, —OCH2R7, —OC(R8)3, —OCH(R8)2, —OCH2R8,and wherein R1 and R2 can be linked together as ring atoms of a substituted or unsubstituted ring selected from the group consisting of cycloalkyl, cycloalkenyl, heterocycle, aryl and mixed ring system;
R7 is selected from the group consisting of halo, hydroxyl, amine, thiol, cyano, carboxyl, optionally substituted (C1-C6)alkyl, optionally substituted (C1-C6)alkenyl, optionally substituted (C2-C6)alkynyl, optionally substituted hetero-(C1-C6)alkyl, optionally substituted hetero-(C1-C6)alkenyl, optionally substituted hetero-(C2-C6)alkynyl, hemiacetal, hemiketal, acetal, ketal, and orthoester; R8 is one or more substituted or unsubstituted rings selected from the group consisting of cycloalkyl, cycloalkenyl, aryl, heterocycle, and mixed ring system; and X is a number from 0 to 3, wherein the metal or metal ions are selected from Li+, Na+, K+, Rb+, Cs+, Be2+, Mg2+, Ca2+, Sr2+, Ba2+, Sc3+, Sc2+, Sc+, Y3+, Y2+, Y+, Ti4+, Ti3+, Ti2+, Zr4+, Zr3+, Zr2+, Hf4+, Hf3+, V5+, V4+, V3+, V2+, Nb5+, Nb4+, Nb3+, Nb2+, Ta5+, Ta4+, Ta3+, Ta2+, Cr6+, Cr5+, Cr4+, Cr3+, Cr2+, Cr+, Cr, Mo6+, Mo5+, Mo4+, Mo3+, Mo2+, Mo+, Mo, W6+, W5+, W4+, W3+, W2+, W+, W, Mn7+, Mn6+, Mn5+, Mn4+, Mn3+, Mn2+, Mn+, Re7+, Re6+, Re5+, Re4+, Re3+, Re2+, Re+, Re, Fe6+, Fe4+, Fe3+, Fe2+, Fe+, Fe, Ru8+, Ru7+, Ru6+, Ru4+, Ru3+, Ru2+, Os8+, Os7+, Os6+, Os5+, Os4+, Os3+, Os2+, Os+, Os, Co5+, Co4+, Co3+, Co2+, Co+, Rh6+, Rh5+, Rh4+, Rh3+, Rh2+, Rh+, Ir6+, Ir5+, Ir4+, Ir3+, Ir2+, Ir+, Ir, Ni3+, Ni2+, Ni+, Ni, Pd6+, Pd4+, Pd2+, Pd+, Pd, Pt6+, Pt5+, Pt4+, Pt3+, Pt2+, Pt+, Cu4+, Cu3+, Cu2+, Ag3+, Ag2+, Ag+, Au5+, Au4+, Au3+, Au2+, Au+, Zn2+, Zn+, Zn, Hg4+, Hg2+, Hg+, B3+, B2+, B+, Al3+, Al2+, Al+, Ga3+, Ga2+, Ga+, In3+, In2+, In1+, Tl3+, Tl+, Si4+, Si3+, Si2+, Si+, Ge4+, Ge3+, Ge2+, Ge+, Ge, Sn4+, Sn2+, Pb4+, Pb2+, As5+, As3+, As2+, As+, Sb5+, Sb3+, Bi5+, Bi3+, Te6+, Te5+, Te4+, Te2+, La3+, La2+, Ce4+, Ce3+, Ce2+, Pr4+, Pr3+, Pr2+, Nd3+, Nd2+, Sm3+, Sm2+, Eu3+, Eu2+, Gd3+, Gd2+, Gd+, Tb4+, Tb3+, Tb2+, Tb+, Db3+, Db2+, Ho3+, Er3+, Tm4+, Tm3+, Tm2+, Yb3+, Yb2+, and Lu3+. |
