| 主权项 |
1. Heterocyclylpyri(mi)dinylpyrazole derivative of formula (I)in which
U represents a structure of formula X1 represents C—H or N, X2 represents S or O, Y represents O, S or N with N being optionally substituted by R5, W represents C, N each of which is optionally substituted by identical or different substituents selected from the group consisting of R5, or represents O if Y equals N, a,b represent a single or double bond
with the proviso that “a” and “b” represent a single bond if W equals O, “a” represents a single bond if Q equals C═C or C—Si and “b” represents a single bond if Y equals O or S, n is 0, 1, 2, 3 or 4, Q represents C, C—C, C═C, C—Si or C—C—C, each of which is optionally mono or polysubstituted by identical or different substituents selected from the group consisting of R5, R1 represents H, C(O)OR7, C(O)SR7, C(S)OR7, C(O)R7, C(S)R7, C(O)NR7R8, C(S)NR7R8, C(O)C(O)R7, C(═NR9)R10, C(═NR9)OR10, C(═NR9)NR9R10, SO(═NR9)R10, SO2NR7R8, SO2R7 or represents C1-C6-alkyl, C3-C8-cycloalkyl, C2-C6-alkenyl, C2-C8-alkynyl, C6-C14-aryl, C2-C9-heterocyclyl, C2-C9-heteroaryl, each of which is optionally mono- or polysubstituted by identical or different substituents selected from the group consisting of R11, R2 represents H, cyano, formyl, OR7, SR7, C(O)OR7, C(O)SR7, C(S)OR7, C(O)R7, C(S)R7 or represents C1-C6-alkyl, C3-C8-cycloalkyl, C2-C6-alkenyl, C2-C8-alkynyl, C6-C14-aryl, C2-C9-heterocyclyl, C2-C9-heteroaryl, each of which is optionally mono- or polysubstituted by identical or different substituents selected from the group consisting of R11, with the proviso that R1 is not H, C1-C6-alkyl, C3-C8-cycloalkyl, C1-C6-haloalkyl, C3-C8-halocycloalkyl, C1-C4-alkoxy-C1-C6-alkyl or amino-C1-C6-alkyl if R2 is H, C1-C6-alkyl, C3-C8-cycloalkyl, C1-C6-haloalkyl, C3-C8-halocycloalkyl, C1-C4-alkoxy-C1-C6-alkyl or amino-C1-C6-alkyl and vice-versa, R3 and R4 represent independently of each other H, F, Cl, Br, I, cyano, nitro, OH, SH or represent C1-C6-alkyl, C3-C6-cycloalkyl, C2-C6-alkenyl, C2-C6-alkinyl, C6-C14-aryl, C1-C4-alkoxy, O—(C6-C14-aryl), S—(C1-C4-alkyl), S(O)—(C1-C6-alkyl), C(O)—(C1-C6-alkyl), C3-C8-trialkylsilyl, heteroaryl, heterocyclyl, each of which is optionally mono- or polysubstituted by identical or different substituents selected from the group consisting of R11 or form together with the carbon atoms, which they are attached to, an optionally mono- or multi identical or different by halogen, oxygen, cyano or C1-C4-alkyl, C1-C4-alkoxy, C1-C6-haloalkyl, C1-C4-haloalkoxy, C3-C6-cycloalkyl substituted cycle with 5 to 8 ring atoms, whereas the cycle comprises carbon atoms but may also contain 1 to 4 heteroatoms selected from oxygen, sulphur or NR14, R5 represents as substituent for C: H, Cyano, Halogen, OH, ═O, C1-C6-alkyl, C2-C6-alkenyl, C2-C6-alkinyl, C1-C6-alkoxy, C3-C6-cycloalkyl, C3-C8-allenyl, C3-C8-trialkylsilyl, C4-C8-cycloalkenyl, C1-C6-alkoxy-C1-C6-alkyl, acyloxy-C1-C6-alkyl, heteroaryl-C1-C6-alkyl, aryl-C1-C6-alkyl, C1-C6-alkylthio-C1-C6-alkyl, C1-C4-alkyl-C(O)—C1-C6-alkyl, C3-C6-cycloalkyl-C(O)—C1-C4-alkyl, heterocyclyl-C(O)—C1-C4-alkyl, C1-C4-alkyl-C(O)O—C1-C6-alkyl, C3-C6-cycloalkyl-C(O)O—C1-C4-alkyl, heterocyclyl-C(O)O—C1-C4-alkyl, heterocyclyl-C1-C6-alkyl, C6-C10-aryl, heterocyclyl, heteroaryl, each of which is optionally mono- or polysubstituted by identical or different substituents selected from the group consisting of OH, F, Cl, Br, I, cyano, NH—C(O)R9, NR9R10, C(O)R9, C(O)OR9, C(O)NR9R10, SO2R9, OC(O)R9 or represents C(O)NR9R10, C(O)R9, C(O)OR9, S(O)2R9, C(S)NR9R10, C(S)R9, S(O)2NR9R10, ═N(OR9) and represents as substituent for N: H, OH, C1-C6-alkyl, C2-C6-alkenyl-C1-C6-alkyl, C2-C6-alkinyl-C1-C6-alkyl, C1-C6-alkoxy, C3-C6-cycloalkyl, C1-C6-alkoxy-C1-C6-alkyl, acyloxy-C1-C6-alkyl, heteroaryl-C1-C6-alkyl, aryl-C1-C6-alkyl, C1-C6-alkylthio-C1-C6-alkyl, C1-C4-alkyl-C(O)—C1-C6-alkyl, C3-C6-cycloalkyl-C(O)—C1-C4-alkyl, heterocyclyl-C(O)—C1-C4-alkyl, C1-C4-alkyl-C(O)O—C1-C6-alkyl, C3-C6-cycloalkyl-C(O)O—C1-C4-alkyl, heterocyclyl-C(O)O—C1-C4-alkyl, heterocyclyl-C1-C6-alkyl, C6-C10-aryl, heterocyclyl, heteroaryl, each of which is optionally mono- or polysubstituted by identical or different substituents selected from the group consisting of OH, F, Cl, Br, I, cyano, NH—C(O)R9, NR9R10, C(O)R9, C(O)OR9, C(O)NR9R10, SO2R9, OC(O)R9 or represents C(O)NR9R10, C(O)R9, C(O)OR9, S(O)2R9, C(S)NR9R10, C(S)R9, S(O)2NR9R10, R6 represents H, cyano, halogen
or represents C1-C6-alkyl, C3-C6-cycloalkyl, heterocyclyl, C2-C8-alkenyl, C2-C8-alkinyl, C1-C8-alkoxy, C2-C8-alkynyloxy, C1-C8-alkylthio, C3-C8-trialkylsilyl, each of which is optionally mono- or polysubstituted by identical or different substituents selected from the group consisting of OH, F, Cl, cyano, R7 and R8 represent H, C(S)R12, C(O)R12, SO2R12, C(O)OR12, OR12 or C(O)NR12R13 or represent C1-C6-alkyl, C2-C6-alkenyl, C2-C6-alkinyl, C3-C8-cycloalkyl, C3-C8-cycloalkenyl, having a two to eight atoms long bridge containing C and O atoms in which two O atoms never follow one another, C6-C14-aryl, benzyl, phenethyl, indanyl, aryloxyalkyl, heteroaryloxyalkyl, heterocyclyl or heteroaryl, each of which is optionally mono- or polysubstituted by identical or different substituents selected from the group consisting of F, Cl, Br, OH, ═O, cyano, nitro, C1-C6-alkyl, C3-C8-cycloalkyl, C1-C6-halogenalkyl, O—C(O)R9, O—P(O)(OR9)2, O—B(OR9)2 or O—(C1-C4-alkyl), O—(C3-C8-cycloalkyl), S—(C1-C4-alkyl), SO—(C1-C4-alkyl), SO2—(C1-C4-alkyl), piperidin, C1-C6-alkylsulfinyl, (C1-C6-alkyl ideneamino)oxy, aryl, heteroaryl, heterocyclyl, alkoxyalkyloxy, NHC(O)H, C(O)R9, C(O)OR9 which is optionally mono- or polysubstituted by identical or different substituents selected from the group consisting of F, Cl, Br, OH, cyano, C1-C6-alkyl, R9 and R10 represent C1-C6-alkyl, C3-C6-cycloalkyl, C2-C6-alkenyl, C2-C6-alkinyl, aryl, benzyl, phenethyl, each of which is optionally mono- or polysubstituted by identical or different substituents selected from the group consisting of F, Cl, Br, I, OH, carbonyl, cyano or represent H, R11 represents OH, F, Cl, Br, I, cyano, ═O, NH—C(O)R9, NR9R10, C(O)R9, C(O)OR9, C(O)NR9R10, SO2R9, OC(O)R9 or represents C1-C6-alkyl, C2-C6-alkenyl, C2-C6-alkinyl, C3-C8-cycloalkyl, C1-C4-alkoxy, C1-C4-alkylthio, O—(C3-C8-cycloalkyl), S—(C3-C8-cycloalkyl), C6-C14-aryl, O—(C6-C14-aryl), S—(C6-C14-aryl), heterocyclyl or heteroaryl, each of which is optionally mono- or polysubstituted by identical or different substituents selected from the group consisting of F, Cl, Br, I, OH, carbonyl, cyano, C1-C6-alkyl or C1-C4-alkoxy, R12 and R13 represent H or represents C1-C6-alkyl, C3-C6-cycloalkyl, C2-C6-alkenyl, C2-C6-alkinyl, C3-C8-cycloalkyl, C6-C14-aryl, heterocyclyl oder heteroaryl, each of which is optionally mono- or polysubstituted by identical or different substituents selected from the group consisting of F, Cl, Br, I, OH, carbonyl, cyano, C1-C6-alkyl or C1-C4-alkoxy, R14 represents H, C1-C6-alkyl, C3-C6-cycloalkyl, C2-C6-alkenyl, C2-C6-alkinyl, C(S)R15, C(O)R15, SO2R15, C(O)OR15, R15 represent H or represents C1-C6-alkyl, C3-C6-cycloalkyl, C2-C6-alkenyl, C2-C6-alkinyl, C3-C8-cycloalkyl, C6-C14-aryl, benzyl, phenethyl, phenoxymethyl, heterocyclyl or heteroaryl, each of which is optionally mono- or polysubstituted by identical or different substituents selected from the group consisting of F, Cl, Br, I, OH, carbonyl, cyano, methyl, ethyl, n-propyl, iso-propyl, n-butyl, iso-butyl, sec-butyl, tert-butyl, n-pentyl, cyclopropyl, or methoxy, ethoxy, n-propoxy, iso-propoxy, n-butoxy, tert-butoxy, methylsulfanyl, nitro, trifluormethyl, difluoromethyl, C(O)R12, C(O)OR12, C(O)NR12R13, SO2R12, OC(O)R12 and/or or an agrochemically active salt thereof. |
