Insecticidal compounds

摘要

A compound of formula (I): wherein A1, A2, A3, A4, A1′, A2′, A3′, A4′, A5′, A6′, G1, R1, R2, R3, R4, R5a and R5b are as defined in claim 1; or a salt or N-oxide thereof. Furthermore, the present invention relates to processes and intermediates for preparing compounds of formula (I) or compounds of formula (I′), to insecticidal, acaricidal, nematicidal and molluscicidal compositions comprising compounds of formula (I) or compounds of formula (I′), and to methods of using compounds of formula (I) or compounds of formula (I′) to combat and control insect, acarine, nematode and mollusc pests.;

主权项

1. A compound of formula (I) or a compound of formula (I′)wherein
A1, A2, A3 and A4, or A1′, A2′, A3′, A4′, A5′, and A6′, are independently of each other C—H, C—R6, or nitrogen; G1 is oxygen or sulfur; R1 is hydrogen, C1-C8alkyl, C1-C8alkoxy, C1-C8alkylcarbonyl-, or C1-C8alkoxycarbonyl-; R2 is the group (z): wherein L is a single bond or C1-C6 alkylene; R2a is hydrogen, or C1-C8alkyl; Y1, Y2 and Y3 are independently of another CR7aR8a, C═O, C═N—OR9a, N—R9a, O, S, SO, SO2, S═N—R9a, or SO═N—R9a, provided that at least one of Y1, Y2 or Y3 is not CR7aR8a; R7a and R8a are independently of another hydrogen, halogen, C1-C8alkyl, or C1-C8haloalkyl; each R9a is independently hydrogen, cyano, nitro, C1-C8alkyl, C1C8haloalkyl, C1-C8alkylcarbonyl-, C1-C8haloalkylcarbonyl-, C1-C8alkoxycarbonyl-, C1-C8haloalkoxycarbonyl-, C1-C8alkylsulfonyl-, C1-C8haloalkylsulfonyl-, aryl-C1-C4alkyl- or aryl-C1-C4alkyl- wherein each aryl moiety is substituted by one to three R11a, or is heteroaryl-C1-C4alkyl- or heteroaryl-C1-C4alkyl- wherein each heteroaryl moiety is substituted by one to three R11a; R11a is independently halogen, cyano, nitro, C1-C8alkyl, C1-C8haloalkyl, C1-C8alkoxy, C1-C8haloalkoxy, or C1-C8alkoxycarbonyl-; R3 is C1-C8haloalkyl; R4 is aryl or aryl substituted by one to five R9, or heteroaryl or heteroaryl substituted by one to five R9; R5a and R5b are, independently of each other, hydrogen, cyano, halogen, C1-C8alkylthio-, C1-C8haloalkylthio-, C1-C8alkylsulfinyl-, C1-C8haloalkylsulfinyl-, C1-C8alkylsulfonyl-, C1-C8haloalkylsulfonyl-, arylthio- or arylthio- wherein the aryl moiety is substituted by one to five R10, arylsulfinyl- or arylsulfinyl- wherein the aryl moiety is substituted by one to five R10, arylsulfonyl- or arylsulfonyl- wherein the aryl moiety is substituted by one to five R10, heterocyclylthio- or heterocyclylthio- wherein the heterocyclyl moiety is substituted by one to five R10, heterocyclylsulfinyl- or heterocyclylsulfinyl- wherein the heterocyclyl moiety is substituted by one to five R10, or heterocyclylsulfonyl- or heterocyclylsulfonyl- wherein the heterocyclyl moiety is substituted by one to five R10, C1-C8alkyl, C1-C8alkyl substituted by one to five R7, C2-C8alkenyl, C2-C8alkynyl, C1-C8haloalkyl, C2-C8haloalkenyl, hydroxy, C1-C8alkoxy, C3-C8alkenyloxy, C3-C8alkynyloxy, or C1 -C8haloalkoxy, provided that at least one of R5a and R5b is not hydrogen; each R7 is independently halogen, cyano, nitro, C3-C10cycloalkyl, C3-C10halocycloalkyl, hydroxy, C1-C8alkoxy, C1-C8haloalkoxy, mercapto, C1-C8alkylthio-, C1-C8haloalkylthio-, C1-C8alkylsulfinyl-, C1-C8haloalkylsulfinyl-, C1-C8alkylsulfonyl-, or C1-C8haloalkylsulfonyl-; and each R6, R9 and R10 is independently halogen, cyano, nitro, C1-C8alkyl, C1-C8haloalkyl, C3-C10cycloalkyl, C3-C10halocycloalkyl, C2-C8alkenyl, C2-C8haloalkenyl, C2-C8alkynyl, C2-C8haloalkynyl, hydroxy, C1-C8alkoxy, C1-C8haloalkoxy, mercapto, C1-C8alkylthio-, C1-C8haloalkylthio-, C1-C8alkylsulfinyl-, C1-C8haloalkylsulfinyl-, C1-C8alkylsulfonyl-, C1-C8haloalkylsulfonyl-, C1-C8alkylcarbonyl-, C1-C8alkoxycarbonyl-, aryl or aryl itself substituted by one to five substituents independently selected from halogen, C1-C4alkyl, C1-C4haloalkyl, C1-C4alkoxy, or C1-C4haloalkoxy, or heterocyclyl or heterocyclyl itself substituted by one to five substituents independently selected from halogen, C1-C4alkyl, C1-C4haloalkyl, C1-C4alkoxy, or C1-C4haloalkoxy;or a salt or N-oxide thereof.