发明名称 |
PROCESS FOR PRODUCING PERFLUOROBUTANESULFONIC ACID SALT |
摘要 |
A process for producing a perfluorobutanesulfonic acid salt (PFBS salt) is provided. By the process, the yield is improved and PFOS salt content is reduced. Electrochemical fluorination is conducted in a reaction solution comprising anhydrous hydrogen fluoride to generate perfluorobutanesulfonyl fluoride, and the fluoride its hydrolyzed to produce a perfluorobutanesulfonic acid salt. The process for producing a perfluorobutanesulfonic acid salt includes: a step in which liquid phase components generated in the electrochemical fluorination cell are withdrawn and a first a perfluorobutanesulfonic acid salt fraction is prepared therefrom; and a step in which gaseous phase components discharged from the electrochemical fluorination cell are collected and a second perfluorobutanesulfonic acid salt fraction is prepared therefrom. The reaction solution in the electrochemical fluorination cell is regulated so as to have a perfluorooctanesulfonyl fluoride content of 500 ppm or lower by withdrawing the liquid phase components from the electrochemical fluorination cell. |
申请公布号 |
EP2530186(A4) |
申请公布日期 |
2014.02.19 |
申请号 |
EP20110737082 |
申请日期 |
2011.01.27 |
申请人 |
MITSUBISHI MATERIALS CORPORATION;MITSUBISHI MATERIALS ELECTRONIC CHEMICALS CO., LTD. |
发明人 |
UOTANI MASAKAZU;KAMIYA TAKESHI;HONDA TSUNETOSHI |
分类号 |
C25B3/08;C07C303/22;C07C309/06 |
主分类号 |
C25B3/08 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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