发明名称 |
POLYMERIZATION INITIATOR FOR LIVING RADICAL POLYMERIZATION |
摘要 |
Provided is a method of living radical polymerization which does not necessitate complicated and intricate synthesis of a dormant species and which is highly efficient. A halogenated derivative compound is used as a dormant species for initiating living radical polymerization. The derivative compound is obtained by halogenating an alcohol compound having a non-conjugated structure or an amine compound having a non-conjugated structure with a halogenating agent capable of halogenating an alcohol or amine. A radical produced by elimination of halogen from the halogenated derivative compound is allowed to react with the unsaturated bond of the monomer. Thus, the monomer, which has a radical-reactive unsaturated bond, is polymerized by living radical polymerization. Preferably, the halogenating agent is a compound (NIS or the like) which also has a function as a catalyst.
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申请公布号 |
US2012136131(A1) |
申请公布日期 |
2012.05.31 |
申请号 |
US201013375853 |
申请日期 |
2010.06.03 |
申请人 |
GOTO ATSUSHI;KIM JEONG SIK;TSUJII YOSHINOBU;FUKUDA TAKESHI;KYOTO UNIVERSITY |
发明人 |
GOTO ATSUSHI;KIM JEONG SIK;TSUJII YOSHINOBU;FUKUDA TAKESHI |
分类号 |
C08G63/78;C08G61/00;C08G63/44 |
主分类号 |
C08G63/78 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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