摘要 |
<P>PROBLEM TO BE SOLVED: To provide a useful catalyst for an asymmetric 1,4-addition reaction to an α,β-unsaturated carbonyl compound. Ž<P>SOLUTION: The 9-aralkyloxy-6'-hydroxy cinchona alkaloid (6) is introduced from 6'-hydroxy cinchona alkaloid (1). (In the formula, R<SP>1</SP>is hydrogen, ethyl or vinyl; R<SP>2</SP>is substituted or nonsubstituted aryl; and X<SP>1</SP>and X<SP>2</SP>are the same or different and each halogen). Ž<P>COPYRIGHT: (C)2010,JPO&INPIT Ž
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