发明名称 METHOD FOR PRODUCING ACROLEIN COMPRISING THE REGENERATION OF A RAW GLYCERIN PHASE
摘要 The invention relates to a method for producing acrolein, comprising the following steps: (a) dehydrating an aqueous glycerin phase G1 in an acrolein reaction region, obtaining an aqueous acrolein reaction phase; (b) at least partially separating the aqueous acrolein reaction phase into an acrolein-rich acrolein phase and an acrolein-poor (in comparison to the acrolein phase) residual phase R1, wherein the residual phase R1 comprises glycerin, water and various remainders from glycerin and water; (c) recycling at least a part of the residual phase R2 in step (a); wherein i) from a glycerin phase G2 comprising remainders that differ from glycerin and water, at least one of said remainders is separated and the thus obtained, purified glycerin phase G2 is immediately supplied to the acrolein reaction region, or ii) at least one remainder different from glycerin and water is separated out of a mixture phase M1 obtained by mixing a glycerin phase G2 with the acrolein-poor residual phase R1, and the thus obtained, purified mixture phase M1 is supplied to the acrolein reaction region. The invention furthermore relates to a method for producing acrylic acid, water-absorbing polymer formations, compounds and hygiene articles, to devices for carrying out the method and their application, to a method for purifying a glycerin phase and to the application of a glycerin phase.
申请公布号 WO2010066513(A1) 申请公布日期 2010.06.17
申请号 WO2009EP64500 申请日期 2009.11.03
申请人 EVONIK STOCKHAUSEN GMBH;STOCHNIOL, GUIDO;BAUMGARTEN, GOETZ;KUPPINGER, FRANZ-FELIX 发明人 STOCHNIOL, GUIDO;BAUMGARTEN, GOETZ;KUPPINGER, FRANZ-FELIX
分类号 C07C45/52;B01J19/00;C07C45/78;C07C45/79;C07C45/82;C07C47/22;C07C57/055;C08F20/06;D01F6/16;D06M16/00 主分类号 C07C45/52
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