4-Amino-1,2,3-benzoxathiazine-derivatives as pesticides

摘要

4-Amino-1,2,3-benzoxathiazine compounds (I) and their salts, are new. 4-Amino-1,2,3-benzoxathiazine compounds of formula (I) and their salts are new. R1-R4 : H, halo, carbamoyl, thiocarbamoyl, nitro, cyano, hydroxy, SF 5 , 1-6C-alkyl, 2-6C-alkenyl, 2-6C-alkynyl, 3-6C-cycloalkyl, 3-6C-cycloalkyl-1-4C-alkyl, 1-4C-alkylthio, 1-4C-alkylsulfinyl, 1-4C-alkylsulfonyl, 1-4C-alkylcarbonyl, 1-6C-alkoxy, 1-6C-alkoxycarbonyl, 3-6C-alkenyloxy, 3-6C-cycloalkyloxy, 3-6C-cycloalkyloxy-1-4C-alkyl, 1-4C-alkoxy-1-4C-alkyl, aryloxy, hetaryloxy, aryl-1-4C-alkyloxy, hetaryl-1-4C-alkyloxy, O-acetyl, (1-4C-alkyl)amino, di-(1-4C-alkyl)amino, 3-6C-trialkylsilyl, aryl, hetaryl, aryl-1-6C-alkyl or hetaryl-1-6C-alkyl, where R1-R4 is unsubstituted or one or more times substituted by T; R5 : H, (1-6C-alkyl)carbonyl, (1-6C-alkoxy)carbonyl, (1-6C-alkylthio)carbonyl, (1-6C-alkyl)thiocarbonyl, (1-6C-alkoxy)thiocarbonyl, (1-6C-alkylthio)thiocarbonyl, 1-8C-alkyl, 3-6C-cycloalkyl, 2-6C-alkenyl, 1-4C-alkoxy, 1-4C-alkylthio, 1-4C-alkylsulfinyl, 1-4C-alkylsulfonyl, aryl, hetaryl, aryl-1-6C-alkyl, hetaryl-1-6C-alkyl or -(C=X)NR7R7a; R6 : H, (1-6C-alkyl)carbonyl, (1-6C-alkoxy)carbonyl, (1-6C-alkylthio)carbonyl, (1-6C-alkyl)thiocarbonyl, (1-6C-alkoxy)thiocarbonyl, (1-6C-alkylthio)thiocarbonyl, 1-8C-alkyl, 3-6C-cycloalkyl, 2-6C-alkenyl, 1-4C-alkylsulfinyl, 1-4C-alkylsulfonyl, aryl, hetaryl, aryl-1-6C-alkyl, hetaryl-1-6C-alkyl or -(C=X)NR7R7a, where R5 and R6 are unsubstituted or one or more times substituted by T; T : halo, cyano, 1-6C-alkyl, 3-8C-cycloalkyl, 1-4C-alkoxy, 1-4C-alkylthio, 1-4C-alkylsulfinyl, 1-4C-alkylsulfonyl, 1-4C-haloalkyl, 1-4C-haloalkoxy, 1-4C-haloalkylthio, (1-4C-alkyl)amino, di-(1-4C-alkyl)amino, aryl or hetaryl; R7 : 1-6C-alkyl, 3-6C-cycloalkyl, 1-6C-alkoxy, 1-6C-haloalkyl, 1-6C-haloalkoxy, aryl or hetaryl (all unsubstituted or one or more times substituted by halo, cyano, nitro, 1-6C-alkyl, 3-6C-cycloalkyl, 1-6C-alkoxy, 1-6C-haloalkyl or 1-6C-haloalkoxy); R7a : H or R7; and X : O or S. Where: R5, R6 together are not for phenylbutyl and hydrogen, if R1 is methoxy; and R1-R4 are not simultaneously hydrogen, if R5 and R6 are hydrogen. Independent claims are included for: (1) composition comprising (I) and nitrogen- or phosphorus-containing salt compound of formula (((R11-D1 +>(R8)(R10)-R9) m) (R12(m-))) (IX) and/or at least one penetration promoter comprising alkoxy compound of formula (R-O-(-AO) v-R1a) (X); and (2) the preparation of (I). D1 : N or P; R8-R11 : H, 1-8C-alkyl (optionally substituted by halo, nitro or cyano) or 1-8C-alkylene (one or more times unsaturated, optionally substituted by halo, nitro or cyano); R12 : inorganic or organic anion; m : 1-4; R : 4-20C-alkyl; R1a : H, methyl, ethyl, n-propyl, iso-propyl, n-butyl, iso-butyl, tert-butyl, n-pentyl or n-hexyl; AO : ethylene oxide, propylene oxide and/or butylene oxide; and v : 2-30. [Image] ACTIVITY : Insecticide; Acaricide; Arachnicide; Anthelmintic; Nematocide; Molluscicide. MECHANISM OF ACTION : None given.