发明名称 |
Reduction of acrylic acid in the production of maleic anhydride |
摘要 |
An improved process for the production of maleic anhydride by the catalytic oxidation of n-butane. Maleic anhydride is produced by reacting n-butane gas with oxygen gas or an oxygen-containing gas, in the presence of a vanadium phosphorus oxide catalyst. A trialkyl phosphite or trialkyl phosphate component is continuously added to the gases in an amount of from about 0.5 ppm to about 4 ppm by weight of elemental phosphorus in the trialkyl phosphate or trialkyl phosphite component. Heat is applied to the gases at a temperature of from about 400° C. to about 440° C. while maintaining a maximum temperature of gases present in the reaction of about 480° C. A simultaneous conversion of n-butane to maleic anhydride of about 84% or more and a conversion of n-butane to by-product acrylic acid of about 1.5% or less is achieved.
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申请公布号 |
US7619099(B2) |
申请公布日期 |
2009.11.17 |
申请号 |
US20060405134 |
申请日期 |
2006.04.17 |
申请人 |
SCIENTIFIC DESIGN COMPANY, INC.;LONZA S.P.A. |
发明人 |
PADIA ASHOK S.;BORTINGER ARIE;MAZZONI GIANLUCA;MONTI TIZIANA |
分类号 |
C07D307/60 |
主分类号 |
C07D307/60 |
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