发明名称
摘要 PROBLEM TO BE SOLVED: To provide a method for producing bis(ethylcyclopentadienyl)ruthenium by which the extremely highly pure bis(ethylcyclopentadienyl)ruthenium can be produced at an inexpensive production cost. SOLUTION: This method for producing bis(ethylcyclopentadienyl)ruthenium comprises carrying out a hydrogenation reaction of bis(acetylcyclopentadienyl) ruthenium in the presence of a catalyst. Any one of a platinum catalyst, a palladium catalyst, a ruthenium catalyst and a Raney nickel catalyst is preferably used as the catalyst. Further, the bis(ethylcyclopentadienyl)ruthenium can be produced at a low cost by using a reaction product of the bis(cyclopentadienyl)ruthenium with acetic anhydride in the presence of a phosphoric acid catalyst, as the bis(acetylcyclopentadienyl)ruthenium.
申请公布号 JP4319748(B2) 申请公布日期 2009.08.26
申请号 JP19990347010 申请日期 1999.12.07
申请人 发明人
分类号 B01J23/42;C07F17/02;B01J23/44;B01J25/02;C07B61/00;C07F15/00;C23C16/18 主分类号 B01J23/42
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