发明名称 METHOD FOR DISPERSING AND FIXING GOLD FINE PARTICLE TO CARRIER, GOLD FINE PARTICLE-DEPOSITED CARRIER OBTAINED THEREBY, CATALYST AND COLORANT
摘要 <P>PROBLEM TO BE SOLVED: To provide a method for easily depositing a nano-ordered gold fine particle or gold cluster on a carrier in a short time regardless of the material of the carrier. <P>SOLUTION: A sublimable gold precursor (a dimethyl-gold-acetylacetonate complex, a dimethyl-gold-trifluoroacetylacetonate complex, a chlorotrimethylphosphine-gold complex, a methyl(trimethylphosphine)-gold complex or the like) and the inorganic or organic carrier (a polymer, an inorganic oxide, activated carbon, a porous metal complex or the like) are mixed in a solid phase at room temperature under normal pressure while imparting mechanical friction to them and then the obtained mixture is deoxidized so that the gold fine particle is dispersed and fixed to the surface of the carrier. The obtained gold nanoparticle- or gold cluster-deposited carrier exhibits excellent characteristics when used as an oxidation catalyst for oxidizing glucose into a gluconic acid, or a colorant. <P>COPYRIGHT: (C)2009,JPO&INPIT
申请公布号 JP2008259993(A) 申请公布日期 2008.10.30
申请号 JP20070106198 申请日期 2007.04.13
申请人 TOKYO METROPOLITAN UNIV 发明人 HARUTA MASAKI;ISHIDA TAMAO;OKUDA IPPEI;KURODA KYOKO;KINOSHITA NAOTO;SUENAGA TOSHIYA;YAMAGUCHI YUSUKE
分类号 B01J23/89;B01J23/52;B01J23/66;B01J31/26;B01J37/00;B01J37/04;B01J37/16;B01J37/18;C07B61/00;C07C27/00;C07C45/39;C07C47/07;C07C49/14;C07C49/78;C07C51/23;C07C51/235;C07C53/08;C07C59/105;C09C1/00;C09C1/44;C09C3/04;C09C3/08 主分类号 B01J23/89
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