A difluoroacetic acid ester is obtained by reacting 1-alkoxy-1,1,2,2-tetrafluoroethane represented by the following formula: HCF<SUB>2</SUB>CF<SUB>2</SUB>OR<SUP>1</SUP> (wherein R<SUP>1</SUP> represents a straight or branched chain alkyl group having 1-20 carbon atoms) with an alcohol having 1-20 carbon atoms and a metal hydroxide or a metal alkoxide for obtaining a difluoroacetic acid metal salt, and then reacting the thus-obtained difluoroacetic acid metal salt with an alcohol having 1-10 carbon atoms in the presence of an acid. This method enables to commercially produce a difluoroacetic acid ester easily by a shorter process when compared with conventional methods. [Chemical formula 5] HCF<SUB>2</SUB>CF<SUB>2</SUB>OR<SUP>1</SUP>
申请公布号
WO2008078479(A1)
申请公布日期
2008.07.03
申请号
WO2007JP72503
申请日期
2007.11.21
申请人
CENTRAL GLASS COMPANY, LIMITED;NISHIMIYA, TAKAYUKI;FUKUI, AKIHIRO;OKAMOTO, SATORU;YOSHIKAWA, SATOSHI;HIBINO, YASUO