发明名称 MULTISTEP PROCESS FOR PREPARING HETEROPHASIC PROPYLENE COPOLYMERS
摘要 A multistage process comprising the following steps: a) polymerizing propylene with optionally one or more monomers selected from ethylene and alpha olefins of formula CH2=CHT1, wherein T1 is a C2-C20 alkyl radical in the presence of a catalysts system, supported on an inert carrier comprising: i) a transition metal compound containing a ligand having a cyclopentadienyl skeleton; and ii) an alumoxane or a compound capable of forming an alkyl metallocene cation; b) contacting, under polymerization conditions, in a gas phase, ethylene with one or more alpha olefins of fonnula CH2 =CHT1, wherein T1 is a C2-C20 alkyl radical, and optionally a non-conjugated diene, in the presence of the polymer obtained in step a), in the presence of a weigh ratio hydrogen/hethylene higher than 1 ppm and optionally in the presence of an additional organo aluminum compound; wherein the amount of the polymer obtained in step a) ranges from 5% by weight and 90% by weight of the polymer obtained in the whole process and the amount of polymer obtained in step b) ranges from 10% by weight and 95% by weight of the polymer obtained in the whole process.
申请公布号 KR20060135607(A) 申请公布日期 2006.12.29
申请号 KR20067004823 申请日期 2006.03.09
申请人 BASELL POLYOLEFINE GMBH 发明人 PELLICONI ANTEO;TONTI MARIA SILVIA;RESCONI LUIGI
分类号 C08F297/08;C08F2/00;C08F4/643;C08F4/659;C08F10/00;C08F210/06;C08L23/08;C08L23/14 主分类号 C08F297/08
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