摘要 |
Novel improved single-phase mixed crystals of monoazo dyes laked with alkaline earth metal cations and ammonium cations in a molar ratio of about 1:2 having a fine particle size and substantially better fastness properties than similar known products are excellently suitable as tinctorially strong pigments. Also claimed is a process for the preparation of a single-phase mixed crystal pigment of formula wherein E is Mg, Ca or Sr, by crystallisation from an inert hydrophilic liquid in the presence of solvated catiens E<SUP>++</SUP>, NR<SUB>5</SUB>R<SUB>6</SUB>R<SUB>7</SUB>R<SUB>8</SUB><SUP>+</SUP>, x is a number from 0.33 to 0.62 and y is a number from 0.76 to 1.34, and the concentration of solvated catiens E<SUP>++</SUP> at the beginning of the crystallisation is higher than the concentration of solvated cations NR<SUB>5</SUB>R<SUB>8</SUB>R<SUB>7</SUB>R<SUB>8</SUB><SUP>+</SUP>.
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