发明名称 Homobimetallic and heterobimetallic alkylidene complexes of ruthenium containing N-heterocyclic carbene ligands
摘要 The invention relates to complexes of ruthenium of the structural formula IwhereX is an anionic ligand,Z is a monodentate to tridentate ligand which contains a metal and is nonionically bound to the ruthenium center,R<1 >and R<2 >are identical or different and are each hydrogen or/and a hydrocarbon group, but may also form a ring, andLigand L is an N-heterocyclic carbene, and also to a process for preparing acyclic olefins having two or more carbon atoms or/and cyclic olefins having three or more carbon atoms and the use of at least one complex of the formula I in olefin metathesis.
申请公布号 US6787620(B2) 申请公布日期 2004.09.07
申请号 US20030371955 申请日期 2003.02.20
申请人 DEGUSSA AG 发明人 HERRMANN WOLFGANG ANTON;KOHL FLORIAN J.;WESKAMP THOMAS
分类号 B01J31/22;C07B37/00;C07B61/00;C07C6/04;C07D249/08;C07F15/00;C07F19/00;C08F4/80;(IPC1-7):C08F4/80;C08F132/02 主分类号 B01J31/22
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