发明名称 Activator solid support for metallocene catalysts in the polymerization of olefins, a process for preparing such a support, and the corresponding catalytic system and polymerization process
摘要 Activator solid support for metallocenes as catalysts in the polymerization of olefins, characterized in that it consists of a group of support particles for a solid catalytic component, which are formed from at least one porous mineral oxide, the said particles having been modified in order to carry, on the surface, aluminium and/or magnesium Lewis-acid sites of formula: groups coming from a functionalization agent having reacted with -OH radicals carried by the base particles of the support, the functionalization reaction having been followed by a fluorination reaction. The catalytic system according to the invention comprises (a) a metallocene catalyst, which has, if required, been subjected to a prealkylation treatment; (b) a cocatalyst; and (c) an activator solid support for metallocene, as defined above, it being possible for the cocatalyst (b) to be absent if the metallocene catalyst (a) has been prealkylated.
申请公布号 US2004014596(A1) 申请公布日期 2004.01.22
申请号 US20030402939 申请日期 2003.04.01
申请人 SAUDEMONT THIERRY;SPITZ ROGER;BROYER JEAN-PIERRE;MALINGE JEAN;VERDEL NATHALIE 发明人 SAUDEMONT THIERRY;SPITZ ROGER;BROYER JEAN-PIERRE;MALINGE JEAN;VERDEL NATHALIE
分类号 C08F4/02;C08F4/60;C08F4/645;C08F4/659;C08F4/6592;C08F10/00;(IPC1-7):B01J31/00;C08F4/44 主分类号 C08F4/02
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