CATALYST SYSTEM AND OLEFIN POLYMERISATION PROCESS

摘要

Methods of making supported chromium catalyst system and processes of polymerizing ethylene using the supported chromium catalyst system are disclosed. A method of forming a catalyst system in a polymerization reactor includes contacting a supported chromium catalyst and a metal alkyl cocataly st by cofeeding the catalyst and cocatalyst to the reactor or feeding the catalyst and cocatalyst separately to the reactor, to form a catalyst system . The catalyst and cocatalyst are not pre-contacted prior to the feeding or cofeeding step. The catalyst system can be contacted with ethylene and optional alpha-olefin comonomer to form polyethylene.