发明名称 |
PROCESS FOR PREPARING TRI(M-SULFOPHENYL)PHOSPHINE BY HYDROLYSIS AND CONTROLLED DILUTION OF THE SULFONATION MIXTURE |
摘要 |
1. Process for the preparation of tri(m-sulphophenyl)phosphine (TPPTS) comprising a) a sulphonation of triphenylphosphine (TPP) by means of a H2 SO4 -SO3 mixture containing an excess of SO3 , b) a hydrolysis of the excess SO3 present in the sulphonate obtained under (a) in order to stop the sulphonation reaction and c) a dilution of the hydrolysate obtained under (b) in order to attain a H2 SO4 normality compatible with d) the final step of extraction of TPPTS, the said process being characterized in that the hydrolysis step (b) and at least a part of the dilution step (c) are carried out simultaneously by incorporating the sulphonate in an acid aqueous hydrolysis solution while maintaining the H2 SO4 normality during the hydrolysis at a value above 9 N and removing at least partly the heat produced, the temperature being below 20 degrees C. |
申请公布号 |
DE3565985(D1) |
申请公布日期 |
1988.12.08 |
申请号 |
DE19853565985 |
申请日期 |
1985.03.22 |
申请人 |
RHONE-POULENC RECHERCHES |
发明人 |
BARRE, CHARLES;DESBOIS, MICHEL;NOUVEL, JACQUES |
分类号 |
C07F9/30;C07F9/50;(IPC1-7):C07F9/50 |
主分类号 |
C07F9/30 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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