发明名称 FLUOROPOLYMER ION EXCHANGER MEMBRANE HAVING EXCELLENT OXIDATION RESISTANCE AND WIDELY RANGING ION EXCHANGE CAPACITY AND MANUFACTURING METHOD THEREOF
摘要 <P>PROBLEM TO BE SOLVED: To provide an ion exchange membrane which is a fluoropolymer ion exchange membrane that is at a low cost and has a wide ion exchange capacity and is particularly suitable for a fuel cell. <P>SOLUTION: The fluoropolymer ion exchange membrane has such characteristics that after a specific hydrocarbon based monomer, an acrylic monomer, or a fluoroethylene monomer are cografted with a long-chain branched polytetrafluoroethylene membrane against the fluorine monomer having a halogen group and polymerizable double bond, the halogen group in a cografted chain is made to be a sodium sulfonate group by a solution of sodium sulfite or sodium hydrogen sulfite, and moreover, it is made to be a sulfon acid group, a grafting ratio of the ion exchange membrane is 10-150%, and an ion exchange capacity is 0.3-3.0 meg/g, and a manufacturing method thereof is also provided. <P>COPYRIGHT: (C)2003,JPO
申请公布号 JP2003261697(A) 申请公布日期 2003.09.19
申请号 JP20020063273 申请日期 2002.03.08
申请人 JAPAN ATOM ENERGY RES INST;NITTO DENKO CORP 发明人 YOSHIDA MASARU;MORITA YOSUKE;SUWA TAKESHI;ASANO MASAHARU;NISHIYAMA SOJI
分类号 C08J5/22;B01J39/04;B01J39/20;B01J47/12;C08F8/36;C08F259/08;H01B1/06;H01B13/00;H01M8/02;H01M8/10 主分类号 C08J5/22
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