摘要 |
A single-site olefin polymerization catalyst and method of making it are disclosed. The catalyst comprises an activator and an organometallic complex . The complex comprises a Group 3 to 10 transition metal, M, and at least one anionic heterocyclobutenyl ligand that is bonded to M. Molecular modeling results indicate that single-site catalysts based on anionic heterocyclobutenyl ligands will have advantages compared with the performanc e of catalysts based on cyclopentadienyl and substituted cyclopentadienyl ligands.
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