| 摘要 |
The invention disclose a hydrogen fluoride containing composition comprising hydrogen fluoride and a compound which is liquid in the standard state (25 DEG C, 1 atmosphere) and has a boiling point of 120 DEG C or more and pka of 12 or more at 25 DEG C, and use of the composition for a fluorination agent. The compound which can be preferably used is represented by the formula (1): <CHEM> wherein R1 to R<4> are a substituted or unsubstituted alkyl or aryl group and can be the same or different, and R1 or R2 or R3 and R4 can bond to form a ring having a nitrogen atom or a nitrogen atom and other hetero atom, or R1 and R3 can bond to form a ring having a nitrogen atom or a nitrogen atom and other hetero atom. The fluorination agent of the invention exerts effect with a similar reaction mechanism to hydrogen fluoride, can be applied to the halogen exchange reaction of a halogen containing organic compound, and can produce a fluorine containing compound with safety and ease without specific equipment or technique. |
