Hydrocarbon drying oil production

摘要

A drying oil is prepared by polymerizing 50 to 100 parts of butadiene-1,3 or a hydrocarbon substituted butadiene, e.g. piperylene, isoprene or dimethylbutadiene, and 50 to 0 parts of styrene or a ring alkylated styrene, e.g. p-methyl styrene, m-methyl styrene, dimethyl styrene or corresponding ethyl homologues, diluted with an inert hydrocarbon diluent, which is liquid at reaction temperatures and pressures, and an alkyl ether or cyclic diether, having oxygen atoms separated by at least 2 carbon atoms, containing 2 to 8 carbon atoms per molecule, e.g. diethyl ether, the diethyl ethers of ethylene glycol and diethylene glycol, diethyl acetal, vinyl isobutyl ether, dihydropyrane, ethylal and dioxane-1,4, in the presence of a finely-divided alkali metal catalyst, e.g. lithium, sodium, potassium, rubidium, caesium, at temperatures from 40 DEG to 95 DEG C. to at least 40 per cent conversion and continuously passing to at least one additional zone at an equal or higher temperature until 100 per cent conversion is obtained. 10 to 50 per cent, based on the catalyst, of an alcoholic promoter, e.g. isopropanol, isobutanol, isopentanol, secondary butanol, tertiary butanol, may be added. The hydrocarbon diluent may be naphtha, Varsol, butane, pentane, benzene, toluene, xylene, cyclohexane, butenes, pentenes or mixtures of these. The catalyst is destroyed by the addition of an acid, e.g. formic, acetic, pentanoic or sulphuric acid, excess of which is neutralized by ammonia and the salts filtered off using a filter aid, e.g. silica gel, clay or charcoal. The ether, alcohol and excess diluent are distilled off and recycled. Further quantities of catalyst, which may be liquid at the higher temperature, and/or promoter may be added to the second zone. Preferably the first zone is charged and reacted to about 80 per cent conversion before the continuous process is commenced. The product may be heated at 120 DEG to 180 DEG C., or at 180 DEG to 210 DEG C. in the presence of maleic acid, acrylonitrile or thioglycolic acid, to effect bodying and improve pigment wetting, and may be concentrated to 99 per cent or more nonvolatile matter to form a clear or light yellow varnish. Cobalt, lead or manganese naphthenates or octoates may be added. In examples: (1) butadiene-1,3 and styrene are polymerized in a three-stage reactor in the presence of dioxane, diethylether, naphtha, sodium and isopropyl alcohol, commencing with a batch-type operation in stage 1 to 80 per cent conversion; (2) a five-stage reactor is employed and a proportion of recycled ether, alcohol and diluent is used.