发明名称 METHOD FOR PRODUCING SYNDIOTACTIC STYRENE COPOLYMER
摘要 PROBLEM TO BE SOLVED: To provide a copolymer which is obtained by introducing a styrene derivative having a methyl group at the meta position into a syndiotactic styrene copolymer, and also provide a method for producing the same. SOLUTION: The copolymer is a syndiotactic styrene copolymer containing a methyl styrene monomer and a styrene monomer, wherein the copolymer has the phenyl groups the C1 carbons of which have their respective tacticities of 30% or more as determined at the racemic pentad in<13> C-NMR. The method for producing the syndiotactic styrene copolymer comprises copolymerizing the methylstyrene monomer and the styrene monomer using a catalyst in the presence of a solvent, wherein the catalyst contains a reaction product between a transition metal compound and at least one promoter for the catalytic component; and the solvent is an aromatic hydrocarbon and/or a halogenated aromatic hydrocarbon having a dielectric constant of 2.0-10.0.
申请公布号 JP2003055413(A) 申请公布日期 2003.02.26
申请号 JP20010249049 申请日期 2001.08.20
申请人 NATIONAL INSTITUTE OF ADVANCED INDUSTRIAL & TECHNOLOGY;KANEGAFUCHI CHEM IND CO LTD;NIPPON STEEL CHEM CO LTD 发明人 KAWABE MASANAO;MURATA MASAHIDE;OZAKI HIROYUKI;KASE TOSHIO;FUKUI YOSHIFUMI;HOAN TE BAN;HAGIWARA HIDEAKI;TSUCHIHARA KENJI;SUZUKI YASUZO;ASAI MICHIHIKO
分类号 C08F4/645;C08F4/6592;C08F212/08;(IPC1-7):C08F212/08 主分类号 C08F4/645
代理机构 代理人
主权项
地址