| 摘要 |
A process is disclosed for producing RCFZH by reaction of an iodide compound of the formula R'CFZI with hydrogen at an elevated temperature, wherein R is SF5, CF2SF5 or RfCF2Y, R' is SF5, CF2SF5 or RfCF2X, Rf is a perfluoroalkylene group containing from 1 to about 12 carbon atoms and optionally containing one or more ether oxygen atoms, Z is selected from F, CF3 and CF2CF3, Y is selected from H, F and SF5, and X is selected from H, F, SF5, and I, provided that when Y is F, X is F, when Y is SF5, X is SF5, and when Y is H, X is H or I.
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