发明名称 OLEFIN POLYMERIZATION CATALYST ACTIVATOR, CATALYTIC SYSTEM, AND POLYMERIZATION PROCESS
摘要 polymerization catalysts. SUBSTANCE: catalyst activator contains cation represented by proton-releasing Broensted acid and inert compatible and coordination-incapable anion, which is defined by general formula [L*-H]+A-, wherein L* is Lewis base containing nitrogen, sulfur, or phosphorus and 1 to 3 C10-C40-alkyl groups with total number of carbon atoms from 12 to 100. Activator exhibits solubility at 25 C in hexane, cyclohexane, or methylcyclohexane at least 5 wt. %. More particularly, activator can be represented by di(octadecyl)methylammonio-tetrakis(pentafluorophenyl) borate or di(hydrogenated tall alkyl) methylammonio-tetrakis(pentafluorophenyl) borate. EFFECT: increased catalytic activity, especially under continuous polymerization conditions in solution. 8 cl, 2 tbl, 4 ex
申请公布号 RU2178422(C2) 申请公布日期 2002.01.20
申请号 RU19980119439 申请日期 1997.03.14
申请人 DZE DAU KEMIKAL KOMPANI 发明人 ROUZEN ROBERT K.;VANDERLENDE DEHNIEHL D.
分类号 B01J31/16;C07F5/02;C08F2/04;C08F4/603;C08F4/619;C08F4/64;C08F4/643;C08F4/659;C08F4/6592;C08F10/00;(IPC1-7):C08F4/603 主分类号 B01J31/16
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