发明名称 |
PROCESS FOR ESTERIFYING 1,3-PROPANEDIOL |
摘要 |
A process that can be used in an esterification and polycondensation processes to produce a polyester such as, for example, poly(trimethylene terephthalate) is disclosed. The process comprises contacting an acid with 1,3-propanediol in the presence of a catalyst comprising tin and titanium. A copolymer that contains up to 20 mole percent of another acid and/or a second alcohol is also disclosed. Further disclosed are a composition of, or comprising, a bis(3-hydroxypropyl) terephthalate prepolymer or a composition of, or comprising, a poly(trimethylene terephthalate) polymer. The bis(3-hydroxypropyl) terephthalate prepolymer and poly(trimethylene terephthalate) can each contain 10 to 100 ppm tin and 10 to 200 ppm titanium relative to the terephthalic acid content.
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申请公布号 |
WO0158983(A1) |
申请公布日期 |
2001.08.16 |
申请号 |
WO2000US21782 |
申请日期 |
2000.08.10 |
申请人 |
E.I. DU PONT DE NEMOURS AND COMPANY |
发明人 |
KURIAN, JOSEPH, V.;LIANG, YUANFENG;PUTZUG, DONALD, EDWARD |
分类号 |
C08G63/16;C08G63/181;C08G63/85;(IPC1-7):C08G63/85;C07C67/08 |
主分类号 |
C08G63/16 |
代理机构 |
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主权项 |
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