发明名称 Lithium exchanged zeolites, process for their preparation and their use as nitrogen adsorbent in air separation
摘要 Production of cation-exchanged low-silicon X zeolites comprises contacting an aqueous slurry of the zeolite with one or more solutions of di- and/or trivalent metal compounds in a high-speed mixer and cation-exchanging the product with lithium. Production of cation-exchanged X zeolites having a silicon/aluminum atomic ratio of less than 1.5, in which 50-95% of the exchangeable cations are lithium, 4-50% are trivalent cations selected from aluminum, scandium, gallium, iron, chromium, indium, yttrium and lanthanides and/or divalent cations selected from calcium, strontium, zinc, copper, chromium, iron, manganese, nickel and cobalt, and 0-15 are residual ions selected from sodium, potassium, ammonium and hydrogen, comprises contacting an aqueous slurry of the zeolite with one or more solutions of di- and/or trivalent metal compounds in a high-speed mixer and cation-exchanging the product with lithium.
申请公布号 EP1116691(A1) 申请公布日期 2001.07.18
申请号 EP20000403498 申请日期 2000.12.13
申请人 CECA S.A. 发明人 PLEE, DOMINIQUE;MASINI, JEAN-JACQUES
分类号 B01D53/02;B01J20/18;B01J20/30;C01B39/02;C01B39/22;(IPC1-7):C01B39/22 主分类号 B01D53/02
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