| 摘要 |
An R-T-B rare earth sintered magnet containing an R2T14B-type intermetallic compound as a main phase and thus having improved squareness ratio is produced by carrying out a reduction and diffusion method comprising the steps of (a) mixing an oxide powder of at least one rare earth element R, a T-containing powder, wherein T is Fe or Fe and Co, a B-containing powder, and a reducing agent such as Ca, (b) heating the resultant mixture at 900 to 1350 DEG C in a non-oxidising atmosphere, (c) removing reaction by-products from the resultant reaction product by washing, and (d) removing Ca by heating the resultant R-T-B rare earth alloy powder at 900 to 1200 DEG C in vacuum at 1.3 mbar (1 Torr) or less, followed by pulverisation of the resultant alloy powder bulk, moulding, sintering in vacuum, heat treatment, and surface treatment. The alloy powder bulk obtained by the heat treatment for Ca removal is preferably pulverised after removal of its surface layer. |
