发明名称 FLUORENE DERIVATIVE AND LIQUID CRYSTAL COMPOSITION INCLUDING THE SAME
摘要 PROBLEM TO BE SOLVED: To obtain a new fluorene-based compound useful as a liquid crystal display element suitable for a ferroelectric liquid crystal display element. SOLUTION: This new fluorene-based compound is expressed by formula I [wherein R1 and R2 are each a (substituted) 1-16C alkyl; X is CH2 or CO; Y is a single bond, OCH2, CH2O or the like; A is (substituted) 1,4-phenylene or 1,4-cyclohexylene] and is e.g. 2-pentyl-7-(4-octylphenyl)fluorene. The compound of formula I is obtained by subjecting a fluorene of formula II to Friedel-Crafts reaction, by reducing the reaction product with hydrazine in the presence of a base, by reacting the reaction product with bromine in a solvent such as chloroform and by subjecting the reaction product and a boronic acid derivative to cross coupling reaction in the presence of a catalyst such as palladium.
申请公布号 JP2000178211(A) 申请公布日期 2000.06.27
申请号 JP19980356225 申请日期 1998.12.15
申请人 CHISSO CORP 发明人 HARUFUJI TATSUJI;OKABE EIJI;SAITO HIDEO
分类号 C07C13/567;C07C25/22;C07C43/20;C07C49/643;C07C49/697;C07C49/755;C09K19/32;G02F1/13;(IPC1-7):C07C13/567 主分类号 C07C13/567
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