TETRAHYDROQUINOLINYL AND INDOLINYL TRIAZINE COMPOUNDS AND PHOTOPOLYMERIZATION INITIATOR CONTAINING THEM

摘要

PURPOSE: Tetrahydroquinolinyl and indolinyl triazine compounds are provided which has a good long preservative quality, photobleaching effect and copolymerization initiator. CONSTITUTION: The tetrahydroquinolinyl and indolinyl triazine compounds(formula 1:R= CnH2n+1(n=0-8), (CH2)nCOOCmH2m+1(n=1-8, m=1-12), (CH2)nO(C2H4O)mCLH2L+1(n=1-8, m=0-4, L=1-12), or CnH2nOR1(R1 is phenyl, thiophenyl, furanyl, benzyl, o-, m-, p-cresyl, n=1-12) are prepared. N-substituted tetrahydroquinoline or indoline are brominated, and cyano compound is synthesized by utilizing CuCN, followed by the reaction with CCl3CN in the presence of AlBr3 to produce triazine compound.