| 摘要 |
1319305 Mixing apparatus UPJOHN CO 17 Nov 1970 [3 Dec 1969] 54635/70 Heading B1C [Also in Divisions B5 and C3] A thermoplastic non-cellular polyurethane is continuously extruded by continuously admixing within a first-zone in the liquid preheated state, a polymeric diol, optionally a difunctional extender, and a catalyst (the ratio of isocyanate to active hydrogen groups being from 0.9:1, to 1.2:1, and the molar proportion of polymeric diol to difunctional extender being from 0.1 to 10:1); continuously passing the reaction mixture through a second zone where the extender may be continuously added (if not added in the first zone), and where it is subjected to high shear mixing; and then continuously passing the reaction mixture through a shaping zone for extrusion as one or more strands (either directly fed to an injection moulding machine or chopped into pellets), the temperature of the mixture being controlled throughout the three zones so that the viscosity is substantially constant at 100,000 cps to 1,000,000 cps. The reaction components may simultaneously be delivered to the feed zone entry port, or the extender may be separately introduced downstream in the first or second zones. Each zone is defined either by separate screw extruders (when the loads thereon may be employed to control the viscosity), or by different locations along the shafts of a twin screw extruder, the temperature being controlled by a plurality of independent means e.g. oil baths therealong which, in the second zone, comprises cooling means. In the first three examples a twin screw mixer-extruder is employed, each shaft whereof comprises a worm section defining the first zone, elliptical kneading elements defining the second zone, and a worm section defining the third zone from which a plurality of strands discharges for collection and cooling under nitrogen on a moving belt, and feeding therefrom to a pelletizer. In Example (4) a mixer-extruder comprised five identical twin screw extruders in series, each shaft thereof comprising a screw section followed by a section comprising triangular paddles, the first extruder being provided with the entry port and the last discharging to the die. The elliptical or triangular kneading elements of the extruders may co-operate with internal barrel projections. The polyurethane may alternatively by pelletised by extrusion of a single strand into a cooling liquid and die face cutting. |
