发明名称 AMPHOTERIC TRANSITION METAL COMPOUNDS, METHOD OF PREPARING THEREOF, METHOD OF POLYMERIZATION OF OLEFINS, AND CATALYST COMPONENT FOR THIS METHOD
摘要 FIELD: chemical industry. SUBSTANCE: described are compounds of general formula I: <EMI ID=0.226 HE=6 WI=27 TI=CHI> wherein L is the same or different and is unsubstituted or substituted cyclopentadienyl group, two L residues are bonded together by means of bridge compound Z wherein Z is SiCR<SP>3</SP>R or Si-(CR<SP>2</SP>-R<SP>3</SP>)XSi,X=0-10, n is 1,2,3 or 4; M is metal of group of Periodic System; X and B form together three to five linked alkyl chain, hydrogen atoms, which is substituted by C<SB>1</SB>-C<SB>20</SB> alkyl group; A is metal of groups IIIa, IIIb of Periodic System; <EMI ID=0.227 HE=3 WI=3 TI=CHI> is same or different and is perfluoridated alkyl or aryl group containing from 1 to 20 carbon atoms; m is 1,2,3,4 or 5. Also described is method of polymerization of olefins and catalysate component of this method. EFFECT: catalyst system having improved activity. 10 cl, 25 ex
申请公布号 RU2140922(C1) 申请公布日期 1999.11.10
申请号 RU19950109885 申请日期 1995.06.09
申请人 KHEKHST AG 发明人 GERKHARD EHRKER;BODO TEMME;MIKHAEHL' AULBAKH;BERND BAKHMANN;FRANK KJUBER
分类号 C07F5/02;C07F7/00;C07F7/08;C07F17/00;C08F4/602;C08F4/619;C08F4/6192;C08F4/643;C08F4/659;C08F4/6592;C08F10/00;C08F110/02;C08F110/06;C08F210/02;C08F210/16;(IPC1-7):C07F5/02 主分类号 C07F5/02
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