发明名称 |
Conductive polymer compositions |
摘要 |
<p>A fluid conductive polymer mixture for use in the preparation of coatings, films and fibres is based on a polyaniline in base form (preferably emeraldine-base form). This is doped with a sulfonic acid having in addition to at least one sulfonic acid group a second hydrogen-bonding functional group and is dispersed in an acid solvent having a pKa less than 4.5 but substantially higher (more positive) than that of the sulfonic acid. The functional sulfonic acid appears to act as a solvating agent, as well as dopant, and allows the formation of high-solids mixtures in the acid solvents (up to around 15 % w/v compared with a maximum of about 10 % in conventional NMP-based mixtures) from which solvent can be extracted with a competing solvent (e.g. in a wet-spinning process); cold- (and hot-) drawable films and fibres can be obtained. Preferred sulfonic acid is 2-acrylamido-2-methyl-1-propanesulfonic acid (AMPSA) or its oligomer and preferred acid solvent dichloroacetic acid. The competing solvent may be acetone, methyl isobutyl ketone or butyl acetate.</p> |
申请公布号 |
AU9637798(A) |
申请公布日期 |
1999.05.31 |
申请号 |
AU19980096377 |
申请日期 |
1998.10.30 |
申请人 |
BICC PUBLIC LIMITED COMPANY |
发明人 |
PHILLIP NORMAN ADAMS;ANDREW PAUL MONKMAN;STEPHEN JOHN POMFRET |
分类号 |
C08L79/00;C09D5/24;C09D179/00;H01B1/12;H01B13/00;(IPC1-7):H01B1/12 |
主分类号 |
C08L79/00 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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