摘要 |
New 11 beta -benzaldoxim-9 alpha ,10 alpha -epoxy-estr-4-ene derivatives (I) and their salts are prepared by oxidation of the corresponding unsaturated compound (II). 11 beta -Benzaldoxim-9 alpha ,10 alpha -epoxy-estr-4-ene derivatives of formula (I) and their salts are new. R<1> = H or 1-6C alkyl; R<2> = H, 1-10C alkyl, aryl, aralkyl, alkylaryl, acyl, CONHR<4> or COOR<4>; R<4> = H, or 1-10C alkyl, aryl, aralkyl or alkylaryl; R<3> = H, 1-10C alkyl, aryl, aralkyl or alkylaryl, (CH2)nCH2Y, OR<5>, (CH2)m-CH=CH(CH2)nR<6> or (CH2)o-C(CR<7>; n = 0-2; Y = F, Cl, Br, I, CN, N3, rhodano, OR<5> or SR<5>; R<5> = H, 1-10C alkyl, aryl, aralkyl, alkylaryl or a 1-10C acyl group (COR<5>); m = 0-3; R<6> = H, OH, 1-10C alkyl, aryl, aralkyl, alkylaryl, alkoxy or acyloxy; o = 0-2; R<7> = H, F, Cl, Br, I, or 1-10C alkyl, aryl, aralkyl, alkylaryl or acyl; Z' = H, 1-10C alkyl, aryl, aralkyl, alkylaryl or acyl, or CONHR<4> or COOR<4> (in Z', R<4> has the meanings given above, but may also be an alkali or alkaline earth metal atom). An Independent claim is also included for preparation of (I).
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