| 发明名称 |
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| 摘要 |
PROBLEM TO BE SOLVED: To obtain the subject by reacting an aromatic halogen compound with an α,β-unsaturated carboxylic acid ester compound in the presence of a catalyst based on a transition metal in the group VIII in carbon dioxide or fluoroform in a specific state in the coexistence of a base such as amines. SOLUTION: This method for producing a cinnamic acid ester derivative comprises reacting an aromatic halogen compound (e.g.; bromobenzene) with an α,β-unsaturated carboxylic acid ester compound (e.g.; methyl acrylate) together with amines (e.g.; methylamine) in the presence of a catalyst of a transition metal in the group VIII [e.g.; Pd(PPh3 )4 ] in carbon dioxide in a super- critical state (scCO2 ) or in fluoroform in the super-critical state (scCHF3 ) preferably at 40-150 deg.C to obtain the objective compound (e.g.; cinnamic acid ethyl ester derivative). |
| 申请公布号 |
JP2879027(B2) |
申请公布日期 |
1999.04.05 |
| 申请号 |
JP19970056727 |
申请日期 |
1997.03.11 |
| 申请人 |
KAGAKU GIJUTSU SHINKO JIGYODAN;NIPPON KOKAN KK |
发明人 |
IKARYA TAKAO;IWASA SEIJI;NOYORI RYOJI |
| 分类号 |
B01J23/44;B01J31/22;C07B61/00;C07C67/343;C07C69/618 |
主分类号 |
B01J23/44 |
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