Process of continuously controlling the pH of an acid liquid including measuring the pH continuously with a glass electrode

摘要

PCT No. PCT/EP93/03675 Sec. 371 Date Jul. 5, 1995 Sec. 102(e) Date Jul. 5, 1995 PCT Filed Dec. 23, 1993 PCT Pub. No. WO94/16369 PCT Pub. Date Jul. 21, 1994The method of continuously controlling pH of an acid scrubbing liquid includes continuously withdrawing a constant partial stream from the scrubbing liquid; continuously measuring a pH in the partial stream with a glass electrode; adding base at a first rate to the partial stream upstream of the glass electrode and continuing the adding until the measured pH is in a pH set-point range of from 2.5 to 11.5; after the pH is in the pH set-point range, changing the first rate of adding base to the constant partial stream to compensate any subsequently occurring pH deviations; during the changing of the first rate of base addition, measuring the first rate of base addition to obtain a measured first rate; and automatically controlling a pH of the acid scrubbing liquid using the measured first rate as a controlling parameter by selecting a rate set-point range of the first rate of adding base to the constant partial stream so that the measured pH can be brought into the pH set-point range of from 2.5 to 11.5 and adding base at a second rate to the acid scrubbing liquid from which the partial steam is withdrawn to compensate for any subsequent fluctuations of the measured first rate from the rate set-point range.