发明名称 |
PROCESS FOR THE PREPARATION OF RANDOM COPOLYMERS |
摘要 |
A process for the copolymerization of a mixture of monomers comprising propylene and 1-butene which comprises contacting the monomers and hydrogen in the gas phase in a single stage reaction zone, under polymerization conditions, with a catalyst system comprising (i) a solid catalyst precursor, which includes magnesium; titanium; a halogen which is chlorine, bromine, or iodine, or a mixture thereof; and a polycarboxylic acid ester containing two coplanar ester groups attached to adjacent carbon atoms; (ii) a hydrocarbyl aluminum cocatalyst; and (iii) a silicon compound containing at least one silicon-oxygen-carbon group, a temperature of from about 50.degree.C to about 90.degree.C, wherein: (a) the atomic ratio of aluminum to titanium is in the range of about 10 to about 300; (b) the molar ratio of aluminum to silicon compound is in the range of about 0.5 to about 10; (c) the propylene partial pressure is in the range of about 50 to about 450 psi; (d) the 1-butene partial pressure is in the range of about 10 to about 50 psi; (e) the hydrogen partial pressure is in the range of about 0.1 psi to about 80 psi; (f) the superficial gas velocity is in the range of about 1 to about 3 feet per second; and (g) the molar ratio of 1-butene to propylene is in the range of about 0.01:1 to about 0.4:1.
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申请公布号 |
CA2029000(C) |
申请公布日期 |
1996.12.24 |
申请号 |
CA19902029000 |
申请日期 |
1990.10.30 |
申请人 |
UNION CARBIDE CHEMICALS AND PLASTICS COMPANY INC. |
发明人 |
TWU, FRED CHUN-CHIEN;FICKER, HAROLD KURT;BURDETT, IAN DONALD |
分类号 |
C08F2/34;C08F4/60;C08F4/658;C08F10/00;C08F210/06;C08F210/08;C08F210/16;(IPC1-7):C08F2/34;C08F210/14 |
主分类号 |
C08F2/34 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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