摘要 |
A cored multi-shell emulsion particle consisting of a core particle, a void layer existing in the exterior of the core particle and a shell layer, each of which has a diameter of phi , d and D, respectively, and the ratio of phi , d and D is in the following range: <MATH> <MATH> The particle exhibits excellent hiding power, brightness, gloss and thermal insulation property as an organic pigment without impairing drying ability and strength of coated layer. The particle can be usefully employed in resin compositions for paper coating, for paints and for thermal recording materials. The particle can be prepared by successive emulsion polymerizations of vinyl monomers (a), (b) and (c) to form a core of polymer (A) coated in order with layers of polymer (B) and polymer (C), wherein monomer (b) is selected to yield a polymer (B) capable of being swelled by contact with alkali; thereafter, polymer (B) is swelled and the resulting particle is dried. |
申请人 |
MITSUI TOATSU CHEMICALS, INC., TOKIO/TOKYO, JP |
发明人 |
HOSHINO, FUTOSHI, KITA-KU, TOKYO, JP;NAKANO, MAKOTO, CHIGASAKI-SHI, KANAGAWA-KEN, JP;SOMEYA, KOUSUKE, YOKOHAMA-SHI, KANAGAWA-KEN, JP;MORITA, JUNKO, YOKOHAMA-SHI, KANAGAWA-KEN, JP;YANAGIHARA, TAKESHI, CHIGASAKI-SHI, KANAGAWA-KEN, JP;YAMAZAKI, AKIHIRO, YOKOHAMA-SHI, KANAGAWA-KEN, JP |