发明名称 |
Process for the preparation of 2-mercaptobenzothiazole |
摘要 |
In a process for the preparation of 2-mercaptobenzothiazole from aniline, sulfur and carbon disulfide under pressure and for separation of the 2-mercaptobenzothiazole from the crude reaction product by cooling and recycling the desirable intermediates and by-products into the reactor together with aniline, sulfur and carbon disulfide, the reaction is carried out using a residence time in the reactor of at least one hour to a time before the 2-mercaptobenzothiazole product thus-formed begins to decompose into undesirable intermediate products. A maximum hydrogen sulfide pressure is maintained on quenching to a temperature ranging between 220 and 280 DEG C. by mixing the crude reaction product with carbon disulfide at a temperature sufficient to obtain a homogeneous quenched mixture. The hydrogen sulfide is removed completely only after crystallization of the 2-mercaptobenzothiazole.
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申请公布号 |
US5367082(A) |
申请公布日期 |
1994.11.22 |
申请号 |
US19930011767 |
申请日期 |
1993.02.01 |
申请人 |
AKZO N.V. |
发明人 |
BERGFELD, MANFRED J.;GUTLEIN, NORBERT;WOHLFAHRT, KLAUS;AUST, EBERHARD |
分类号 |
C07D277/72;(IPC1-7):C07D277/72 |
主分类号 |
C07D277/72 |
代理机构 |
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地址 |
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