摘要 |
Disclosed is a process for making ethyl acetate which comprises reacting in a reaction zone ethyanol and molecular oxygen in the presence of a solid catalyst containing the elements and proportions indicated by the empirical formula PdaMbTiPcOx(formula 1) where M is selected from Cd, Au, Zn, Tl, alkali metals and alkaline earth metals, a is from 0.0005 to 0.2 b is from zero to 3a c is 0.5 to 2.5, and x is a value sufficient to satisfy the valence requirements of the other elements present, and wherein said catalyst contains crystalline TiP2O7.
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