发明名称 Aluminum fluoride catalyst compositions and use thereof in a chlorofluorination process for preparing 1,1-dichloro-1,2,2,2-tetrafluoroethane
摘要 A catalyst composition is disclosed which consists essentially of an aluminum fluoride prepared by the reaction of aluminum hydroxide and HF. Also disclosed is a process for preparing 1,1,-dichloro-1,2,2,2-tetrafluoroethane by chlorofluorination which comprises the step of contacting a gaseous mixture comprising at least one tetrahaloethylene having the formula C2Cl4-xFx wherein x is an integer from zero to 3 and both Cl2 and HF with said catalyst composition at an elevated temperature; and a process for producing 2-chloro-1,1,1,2-tetrafluoroethane and/or 1,1,1,2-tetrafluoroethane by hydrodechlorinating 1,1-dichloro-1,2,2,2-tetrafluoroethane prepared by said chlorofluorination.
申请公布号 US5243108(A) 申请公布日期 1993.09.07
申请号 US19920865807 申请日期 1992.04.07
申请人 E. I. DU PONT DE NEMOURS AND COMPANY 发明人 MANZER, LEO E.;TEBBE, FREDERICK N.
分类号 B01J27/125;C07C17/04;C07C17/08;C07C17/21;C07C17/23;C07C19/12 主分类号 B01J27/125
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