发明名称 PRODUCTION OF VINYLCYCLOHEXANE
摘要 PURPOSE:To provide the subject compound useful as a raw material for heat- resistant resins, a comonomer for polyolefins, etc., in a high selectivity by subjecting 1-cyclohexylethanol to a dehydrative reaction in the presence of zirconium oxide as a catalyst. CONSTITUTION:1-Cyclohexylethanol is subjected to a dehydrative reaction in the presence of zirconium oxide as a catalyst at 200-500 deg.C, preferably 300-400 deg.C, to produce vinylcyclohexane. The zirconium oxide catalyst is preferably obtained by calcining a zirconium compound as the catalyst at 300-1500 deg.C, preferably 500-11OO deg.C, for 0.1-50hrs, preferably 1-10hrs.
申请公布号 JPH054931(A) 申请公布日期 1993.01.14
申请号 JP19910318810 申请日期 1991.12.03
申请人 SUMITOMO CHEM CO LTD 发明人 ARAKI MASASHI;TAKAHASHI KAZUMITSU;HIBI TAKAO
分类号 B01J21/06;C07B61/00;C07C1/24;C07C13/19 主分类号 B01J21/06
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