Process for preparing propylene block copolymers.

摘要

In a two-step polymerization of propylene under the catalysis by a Ziegler catalyst comprising (A) a titanium-containing solid catalyst component such as that based on TiCl3 or TiCl4 preferably supported on a magnesium compound and (B) an organoaluminum component wherein a crystalline propylene polymer is prepared in the first step and a rubbery propylene copolymer is prepared in the second step thereby to produce a propylene block copolymer or a chemically blended propylene polymer, the improvement which comprises the use as the titanium-containing solid catalyst of that which has undergone a preliminary polymerization of a diolefin compound of 4 to 18 carbon atoms polymerized thereon. Tackiness of propylene block copolymers or chemically blended propylene polymers which is likely to accompany such polymers is reduced.