| 摘要 |
A new class of polymers and processes used in their preparation are described. These polymers are comprised of crosslinkable aramids, especially aramids that are based on synthetic aromatic amino acids. The aromatic amino acids suggested for this application are selected from the classes of amino benzoic acids, aminodiphenyl carboxylic acids, aminodiphenyl ether carboxylic acids, aminodiphenyl sulfide carboxylic acids, amino diphenyl sulfoxide-and sulfone carboxylic acids, aminonaphtalene carboxylic acids, amino anthracene carboxylic acids as well as their sulfonic acid counterparts, aminopyrimidine carboxylic acids and their crosslinkable and potentially crosslinkable derivatives. Crosslinkable or potentially crosslinkable moieties are selected from a group comprising amino-, nitro-, cyano-, halogene, acetylene, vinyl, acrylic moieties. Crosslinking can be achieved after linear polymers of high molecular weight are produced from low molecular weight prepolymers. Depending upon the crosslinkable groups(s) available on the amino acids, multifunctional epoxides, isocyanates, quinones, anhydrides, aziridines, titanates, zirconyl salts, preformed epoxy-or phenolic resins, radical or ionic polymerization catalysts can be used for curing. Polymers can be prepared either from a single amino acid or a combination of different amino acids to obtain polymers with varying characteristics.
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