发明名称 PROCESS FOR PRODUCING HEAT-SHRINKABLE POLYETHYLENE FILM
摘要 A process for producing heat-shrinkable polyethylene film having less thickness variation in a mottled pattern, excellent low-temperature heat-shrinking properties and excellent transparency, which comprises conducting tubular stretching under specific stretching temperature conditions of a resin composition mainly comprising a copolymer composed of ethylene and 1 to 10 % of at least one C4-C12 alpha -olefin and having a melting point of 0.3 to 2.0 g/10 min and a density of 0.86 to 0.92 g/cm<3> at 25 DEG C, more preferably a composition having an endothermic area below the melting point of 55 % or more based on the whole endothermic area in the melting curve obtained by using a differential scanning calorimeter. No excellent properties could be obtained by conventional linear low-density polyethylene having a g< eta > (=[n]/[n]L; wherein [n] is a limiting viscosity of a polymer and [n]L is a limiting viscosity of a straight chain polymer of the same average molecular weight as that of the said polymer) of 0.3 to 0.7 which showed good transparency but which, in tubular bi-axial stretching, showed unstable stretchability, providing stretched film with large thickness variation in a mottled pattern.
申请公布号 WO8901402(A1) 申请公布日期 1989.02.23
申请号 WO1988JP00807 申请日期 1988.08.15
申请人 KOHJIN CO., LTD. 发明人 ISOZAKI, HIDEO;MIZUTANI, TOMOZI
分类号 B29C55/24;B29C55/26;B29C55/28;B29C61/00;B29C61/08;B29K23/00;B29K105/02;B29L7/00;B29L23/00;C08J5/18;(IPC1-7):B29C61/08 主分类号 B29C55/24
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