发明名称 Process for preparing the lactone 2-ethylidene-6-hepten-5-olide by telomerisation of butadiene and carbon dioxide
摘要 The present invention relates to a process for preparing the lactone 2-ethylidene-6-hepten-5-olide <IMAGE> by telomerisation of butadiene and carbon dioxide in the presence of a catalyst belonging to the group of cationic complexes of palladium. Process characterised in that the cationic complexes contain ligands, either nitriles, or phosphines, or nitriles and phosphines, or nitriles, phosphines and halides, or phosphines and halides, or alternatively chelating agents in which one of the coordinating atoms is covalently linked to the metal, it being possible for the other to be either nitrogen, or phosphorus, or oxygen, or alternatively sulphur.
申请公布号 FR2617163(A1) 申请公布日期 1988.12.30
申请号 FR19870008911 申请日期 1987.06.23
申请人 STRASBOURG I UNIVERSITE 发明人 DOMINIQUE NOBEL;DOMINIQUE MATT;PIERRE BRAUNSTEIN
分类号 B01J31/16;B01J31/18;B01J31/24;C07D309/32;(IPC1-7):C07D309/30;B01J31/20;B01J27/14 主分类号 B01J31/16
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