发明名称 POLYMERIZATION OF ETHYLENE AND ALPHA-OLEFIN
摘要 PURPOSE:To polymerize ethylene and alpha-olefin, wherein the production cost of the catalyst is reduced and the catalyst exhibits an excellent activity, by polymerizing ethylene and alpha-olefin in the presence of a specified supported Ti catalyst. CONSTITUTION:1g of a carrier obtained by pulverizing a complex of Mg, a halogen and an electron-donating compound or of an electron-donating compound and an electron-accepting compound together and 20ml or TiCl4 are heated at 80 deg.C in a (halogenated) hydrocarbon solvent for 2hr, after which the resultant is washed with a large amount of n-heptane to give a supported Ti ingredient A which supports TiCl4 in an amount of 3-5 times by weight of the standard amount. Ethylene and alpha-olefin are polymerized in the presence of a catalyst consisting of the ingredient A, an organoaluminum compound B and, if necessary, an electron-donating compound or an electron-accepting compound C at -50-200 deg.C under normal pressure to 200kg/cm<2>G.
申请公布号 JPS63159407(A) 申请公布日期 1988.07.02
申请号 JP19860306209 申请日期 1986.12.24
申请人 MITSUI TOATSU CHEM INC 发明人 ITO AKIRA
分类号 C08F4/64;C08F4/60;C08F4/654;C08F10/00;C08F110/00;C08F110/02 主分类号 C08F4/64
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