发明名称 PRODUCTION OF PARAFORMALDEHYDE HAVING HIGH FORMALDEHYDE CONTENT
摘要 PURPOSE:To obtain the titled compound, by making a slightly soluble basic alkaline earth metallic compound into finely divided solid or alcoholic suspension and adding the solid or the alcoholic suspension to a concentrated aqueous solution of formaldehyde or slurry just before solidification under cooling or during solidification under cooling and drying the solution or the slurry. CONSTITUTION:A concentrated aqueous solution of formaldehyde having <=75-<85wt% concentration is solidified under cooling and dried to give paraformaldehyde having high formaldehyde content. In the production, slightly soluble alkaline earth metallic compound (0.01-0.1wt% solubility in water) such as magnesium oxide, calcium oxide or calcium carbonate is processed into finely divided solid or suspension in a lower alcohol as a liquid medium and a small amount (about 20-100ppm, especially 40-60ppm based on paraformaldehyde) is added to the concentrated aqueous solution of formaldehyde or slurry just before solidification under cooling or during solidification under cooling and the solution or the slurry is dried.
申请公布号 JPS62148442(A) 申请公布日期 1987.07.02
申请号 JP19850289335 申请日期 1985.12.24
申请人 MITSUI TOATSU CHEM INC 发明人 SAKAGUCHI YASUHIKO;YOSHIMURA KEIICHIRO
分类号 C07C47/04;C07C41/58;C07C43/317;C07C45/00;C07C45/78;C07C67/00 主分类号 C07C47/04
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