发明名称 |
PRODUCTION OF PROPYLENE GLYCOL MONOOLEATE |
摘要 |
<p>PURPOSE:To obtain the titled substance, by producing a sufficiently purified oleic acid from an organic solvent solution of urea and a fatty acid mixture containing oleic acid and adding propylene oxide to the oleic acid using a tertiary amine or quaternary ammonium salt as a catalyst. CONSTITUTION:Urea and a fatty acid mixture containing oleic acid are dissolved in an organic solvent (e.g. methanol) and the solution is cooled to remove >=16C higher saturated fatty acids and higher mono-unsaturated fatty acids having larger carbon number than oleic acid from the solution as a urea adduct crystal. The residual organic solvent solution is partially saponified with a base to form an acidic salt of oleic acid. Since the salt forms an easily filterable crystal by forming an adduct with a small amount of residual urea, the removal of impurities can be carried out in high efficiency and a high-purity oleic acid can be produced. The titled colorless and odorless substance having high stability can be produced by adding propylene oxide to the high-purity oleic acid using a tertiary amine or a quaternary ammonium salt as a catalyst. USE:Emulsifier for foods and pharmaceuticals.</p> |
申请公布号 |
JPS62138451(A) |
申请公布日期 |
1987.06.22 |
申请号 |
JP19850276911 |
申请日期 |
1985.12.11 |
申请人 |
NIPPON OIL & FATS CO LTD |
发明人 |
KUBO YOSHIFUMI;SUZUKI MASAO;SUGINAKA AKINORI;AKIMOTO SHINICHI |
分类号 |
C07C69/675;B01J31/02;C07B61/00;C07C67/08;C07C67/24;C07C69/732 |
主分类号 |
C07C69/675 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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